A repository with teaching and tutorial materials for electrochemical impedance spectroscopy. This is currently under construction. Most of the materials are developed using Python 3 and many of the packages that makes up the "SciPy-stack". Contributions are most welcome (soon CONTRIBUTING.md will be available).
Table of Contents
- interactive impedance simulations
- lessons
- tutorials
- links to useful online resources
- Elchemea Analytical is an easy to use impedance fitting and plotting application that is available to download and install, or use directly online through your browser. It is free and open source software distributed under the GNU GPL. OS: Linux
- EIS Spectrum Analyser is a standalone program for analysis and simulation of impedance spectra. It has also a built-in impedance spectra simulation routine, tools for impedance data processing (subtraction of circuit elements and subcircuits, normalisation for electrode surface area) and plotting in various formats. The program is free for noncommercial use. OS: Windows
- Impedance Analyzer is an open-source, web-based analysis platform (currently a beta version) aimed at making physics-based models as easy to use as equivalent circuits for quantitative analysis of EIS experimental data. Docs and Online version, as it is currently being developed there are good opportunities to contribute with ideas, feedback, documentation, or programming.[]
Kramers-Kronig transform compliance testing is a valuable tool for quantification of errors in impedance spectroscopy data. There are currently a number of tools freely available that implements the method proposed by B.A. Boukamp in his article "A Linear Kronig-Kramers Transform Test for Immittance Data Validation" [1,2].
- Boukamp's KKtest for Windows is free for non-commercial use and can be downloaded from https://www.utwente.nl/en/tnw/ims/publications/downloads/KK-windows.zip
- EIS Spectrum Analyser also incorporates the linear KK transform test docs here
- The Lin-KK tool is a more recent piece of software from the and incorporates a few advanced features to protect against over/under-fitting during Kramers-Kronig validity tests of the impedance spectra. This page also has a nice introduction to the method and the algorithm used is discussed in [3,4] https://www.iam.kit.edu/wet/english/Lin-KK.php
Distribution of Relaxation Times [add references here] is a non-parametric approach to analysis of impedance spectroscopy data which has proven particularly useful for analysis of data from devices such as fuel cells and electrolyzers, but has found application in many other areas too.
- DRTtools: The Ciucci group has developed a free and open source Matlab toolbox (which includes a GUI), released under a GNU licence, that can be used to compute the DRT of EIS data, using an algorithm involving Tikhonov regularization.[5,6,7]
[1] B.A. Boukamp, "A Linear Kronig-Kramers Transform Test for Immittance Data Validation", Journal of the Electrochemical Society. 142 (1995) 1885–1894, https://doi.org/10.1149%2F1.2044210
[2] B. A. Boukamp, Solid State Ionics, 169, 65–73 (2004), https://doi.org/10.1016%2Fj.ssi.2003.07.002
[3] M. Schönleber and E. Ivers-Tiffée, "Approximability of impedance spectra by RC elements and implications for impedance analysis", Electrochemistry Communications 58 (2015) 15-19, https://dx.doi.org/10.1016/j.elecom.2015.05.018
[4] M. Schönleber, D. Klotz and E. Ivers-Tiffée, "A Method for Improving the Robustness of linear Kramers-Kronig Validity Tests", Electrochimica Acta (2014), https://dx.doi.org/10.1016/j.electacta.2014.01.034
[5] M. Saccoccio, T.H. Wan, C. Chen, and F. Ciucci. "Optimal Regularization in Distribution of Relaxation Times Applied to Electrochemical Impedance Spectroscopy: Ridge and Lasso Regression Methods – a Theoretical and Experimental Study." Electrochimica Acta, 147, 470-482 (2014),
[6] F. Ciucci and C. Chen. "Analysis of Electrochemical Impedance Spectroscopy Data Using the Distribution of Relaxation Times: A Bayesian and Hierarchical Bayesian Approach." Electrochimica Acta, 167, 439-454 (2015),
[7] T.H. Wan, M. Saccoccio, C. Chen, and F. Ciucci. "Influence of the Discretization Methods on the Distribution of Relaxation Times Deconvolution: Implementing Radial Basis Functions with DRTtools." Electrochimica Acta, 184, 483–499 (2015),