Copy the CSS file somewhere, and follow the official instruction.
I have this piece in my Emacs configuration that allows me to globally specify a CSS file to embed automatically, which I shamelessly copied from here.
;; Embed inline CSS read from a file.
(defun my-org-inline-css-hook (exporter)
"Insert custom inline css"
(when (eq exporter 'html)
(let* ((dir (ignore-errors (file-name-directory (buffer-file-name))))
(path (concat dir "style.css"))
(homestyle (and (or (null dir) (null (file-exists-p path)))
(not (null-or-unboundp 'my-org-inline-css-file))))
(final (if homestyle my-org-inline-css-file path)))
(if (file-exists-p final)
(progn
(setq-local org-html-head-include-default-style nil)
(setq-local org-html-head (concat
"<style type=\"text/css\">\n"
"<!--/*--><![CDATA[/*><!--*/\n"
(with-temp-buffer
(insert-file-contents final)
(buffer-string))
"/*]]>*/-->\n"
"</style>\n")))))))
(add-hook 'org-export-before-processing-hook 'my-org-inline-css-hook)